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Question: Identify all of the McLafferty rearrangement products of N-ethyl 2-methylpentanamide
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Identify all of the McLafferty rearrangement products of N-ethyl 2-methylpentanamide:
Select one or more:
- a. ethene (ethylene)
- b. propene
- c. ionized 2-methylpentenamide (in tautomeric form)
- d. ionized N-ethyl propanamide (in tautomeric form)
- e. ionized N-ethyl 2-methylpropenamide (in tautomeric form)
- f. pentene
- g. ionized 2-methylpentanamide (in tautomeric form)
Anwer
Draw the substitution products for each of the following reactions; if the products can exist as stereoisomers, show what stereoisomers are obtained:
a. (R) – 2 -bromopentane +CH3O−+CH3O−
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b. (R)−3 -bromo- 3 -methylheptane +CH3OH
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c. benzyl chloride +CH3CH2OH+CH3CH2OH
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d. allyl chloride +CH3OH+CH3OH
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e. 1 -bromo- 2 -butene +CH3O−+CH3O−
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f. 1 -bromo- 2 -butene +CH3OH+CH3OH
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