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Home/ Questions/Draw the neutral organic product for the following reaction.
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lyytutoria
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lyytutoriaExpert
Asked: April 13, 20222022-04-13T05:52:26+00:00 2022-04-13T05:52:26+00:00In: Chemistry

Draw the neutral organic product for the following reaction.

  • 11

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Draw%20the%20neutral%20organic%20product%20for%20the%20following%20reaction.%20Show%20stereochemistry%20clearly.%20Draw%20the%20neutral%20organic...

Draw the neutral organic product for the following reaction. Show stereochemistry clearly.

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♦ Relevant knowledge

A reaction between two organic substances using different reagents under various reaction conditions to produce an organic compound with different properties is known by the term organic reaction.
neutralorganic
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    lyytutoria Expert
    2022-04-27T10:42:05+00:00Added an answer on April 27, 2022 at 10:42 am
    Concepts and Reason
    Reduce Alkynes to trans-Alkenes An alkyne can be described as an unsaturated hydrocarbon that has a triple carbon-carbon bond ( ). In the presence of sodium or lithium, the carbon-carbon triple bonds can react to form a trans-alkene with a carbon-carbon( C = C).
    Anti-addition:
    Anti-addition can be defined as adding two substitutes to the opposite ends of a triple-bonded to create the anti-addition product.
    Fundamentals
    Reaction of alkyne and Li metal A trans-alkene of an alkyne is formed by combining it with lithium metal in an aromatic ethylamine solvent. The solvent can also act as a reducing agent and then the ammonium chloride salt is added. This is an example: R-C5
-R
1. Li, CH3CH2NH2
–
2. NH4Cl
Alkyne
R
Trans Alkene
Mechanism: nm
-
Ice
cream
R
-c
ác-R
Li
–
c=ce L:
CH3NH
Alkyne
Ć
+ CH3NH® Li®
=
+ CH3NH® Li®
H
R.
trans-alkene
C2H5NH

    Formation intermediate of radical anion: C=
C-
c=ce L®
Alkyne
Formation and use of vinyl radicals: c=ce L®
CHÚNH
+ C2H5NHPL:
Formation and use of vinylic anion Formation of the trans-alkene - Bing
+ C2H3NH® Li®
C2H5NH
trans-alkene
anti addition product
Ans: | 1. 2 Li, C,H,NH, -78 °C
-
2. NHCl
0-
Trans product

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  2. Mia Martin
    2022-04-13T05:55:19+00:00Added an answer on April 13, 2022 at 5:55 am
    Concepts and Reason

    Reduce Alkynes to trans-Alkenes

    An alkyne can be described as an unsaturated hydrocarbon that has a triple carbon-carbon bond ( ). In the presence of sodium or lithium, the carbon-carbon triple bonds can react to form a trans-alkene with a carbon-carbon ( C=C
).

    Anti-addition:

    Anti-addition can be defined as adding two substitutes to the opposite ends of a triple-bonded to create the anti-addition product.

    Fundamentals

    Reaction of alkyne and Li metal

    A trans-alkene of an alkyne is formed by combining it with lithium metal in an aromatic ethylamine solvent. The solvent can also act as a reducing agent and then the ammonium chloride salt is added. This is an example:


    R-C5
-R
1. Li, CH3CH2NH2
–
2. NH4Cl
Alkyne
R
Trans Alkene

    Mechanism:


    nm
-
Ice
cream
R
-c
ác-R
Li
–
c=ce L:
CH3NH
Alkyne
Ć
+ CH3NH® Li®
=
+ CH3NH® Li®
H
R.
trans-alkene
C2H5NH


    Formation intermediate of radical anion:


    C=
C-
c=ce L®
Alkyne


    Formation and use of vinyl radicals:


    c=ce L®
CHÚNH
+ C2H5NHPL:


    Formation and use of vinylic anion



    Formation of the trans-alkene


    - Bing
+ C2H3NH® Li®
C2H5NH
trans-alkene
anti addition product

    Ans:


    | 1. 2 Li, C,H,NH, -78 °C
-
2. NHCl
0-
Trans product

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